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Artigo Acesso aberto Revisado por pares
BIBTEX RIS

Regioselective enzymic deacetylation of octa-O-acetyl-sucrose: preparation of hepta-O-acetylsucroses

1991; Elsevier BV; Volume: 222; Linguagem: Inglês

10.1016/0008-6215(91)89011-4

ISSN

1873-426X

Autores

Kung‐Yao Chang, Shih‐Hsiung Wu, Kung‐Tsung Wang,

Tópico(s)

Enzyme Production and Characterization

Resumo

Deacetylation of octa-O-acetylsucrose (1) with Alcalase or protease N gave the 2,3,4,6,3',4',6'-hepta-acetate (2) as the initial major product with the 2,3,4,6,3',4'-hexa-acetate (3) as the subsequent main product. The 2,3,4,1',3',4',6'-hepta-acetate (5) was obtained from 1 by the action of lipase OF or lipase AP6, and the 2,3,4,6,1',3',6'-(4) and 2,3,4,6,1',3',4'-hepta-acetate (7) by the action of Candida lipase and chymotrypsin, respectively. The 2,3,6,1',3',4',6'-hepta-acetate (6) was formed from 5 by acyl migration.

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