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A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

2013; Royal Society of Chemistry; Volume: 49; Issue: 74 Linguagem: Inglês

10.1039/c3cc44064h

1364-548X

Paula Rubio‐Marqués, Antonio Leyva‐Pérez, Avelino Corma,

Catalytic Cross-Coupling Reactions

Nitroderivatives are transformed to cyclohexylanilines at room temperature in good yields and selectivity via a hydrogenation-amine coupling cascade reaction using Pd nanoparticles on carbon as a catalyst and a Brönsted acid.