Multielectron Contribution to Near-Edge X-Ray Absorption
1982; American Physical Society; Volume: 49; Issue: 18 Linguagem: Inglês
10.1103/physrevlett.49.1353
ISSN1092-0145
Autores Tópico(s)Advanced Chemical Physics Studies
ResumoBy comparison with photoelectron spectra which contain multielectron shakeup satellites, evidence is found for a structure in x-ray absorption near-edge spectra in Mn${\mathrm{Cl}}_{2}$, Fe${\mathrm{Cl}}_{2}$, and Co${\mathrm{Cl}}_{2}$ produced by these same shakeup transitions. The strength of these shakeup satellites in absorption is weaker than in photoemission, as expected because of the different excitation energy of the photoelectrons involved.
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