Electronic Properties of Conjugated Polyelectrolyte Thin Films
2008; American Chemical Society; Volume: 130; Issue: 31 Linguagem: Inglês
10.1021/ja801451e
ISSN1943-2984
AutoresJung Hwa Seo, Thuc‐Quyen Nguyen,
Tópico(s)Organic Electronics and Photovoltaics
ResumoThe electronic properties of conjugated polyelectrolytes (CPEs) with poly(fluorene-co-phenylene) backbones and different counterions and charges have been investigated using absorption and ultraviolet photoelectron spectroscopy (UPS). The optical energy band gap of CPEs depends mainly on their conjugated backbone and are nearly insensitive to the charges or counterions. UPS measurements reveal that electron injection from Au to polymers with cationic groups is more efficient than for the neutral and anionic counterparts. The vacuum levels of CPEs were also shifted toward higher or lower binding energy, relative to that of Au, depending on the charge and counterion presence, and provide insight into the general alignment of dipoles at the metal/organic interface.
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