An Isocyanide Radical as Complex Ligand
1986; Wiley; Volume: 25; Issue: 8 Linguagem: Inglês
10.1002/anie.198607441
ISSN1521-3773
AutoresFriedrich Seitz, Helmut Fischer, Jürgen Riede, Thomas Schöttle, Wolfgang Kaim,
Tópico(s)Photochromic and Fluorescence Chemistry
ResumoThe stable, neutral complexes 1 and 2, containing the dimesitylmethyl(isocyano) radical , are formed via a SET (single electron transfer) mechanism from the corresponding 2‐azaallenylidene complexes. The structure of 1 (violet crystals) was established by X‐ray structure analysis (R = mesityl). equation image
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