Artigo Revisado por pares

Reactions of Ru3(CO)12 with nitrobenzene and aniline

1973; Elsevier BV; Volume: 61; Linguagem: Inglês

10.1016/s0022-328x(00)86569-9

ISSN

1872-8561

Autores

Enrico Sappa, Luciano Milone,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

Nitrobenzene and aniline react with Ru3(CO)12 to yield the following trinuclear compounds: Ru3(CO)10NPh, Ru3(CO)9(NPh)2. HRu3(CO)10NHPh, and H2Ru3(CO)9NPh. Structural proposals for those products are made on the basis of instrumental analysis. Their properties are described and some comments on their reactivity are made.

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