
Molecular Vibrations of Quinones. IV. Raman Spectra of p -Benzoquinone and Its Centrosymmetrically Substituted Isotopic Derivatives and Assignment of Observed Frequencies
1965; American Institute of Physics; Volume: 42; Issue: 3 Linguagem: Inglês
10.1063/1.1696083
ISSN1520-9032
AutoresH. Stammreich, Th. Teixeira Sans,
Tópico(s)Nonlinear Optical Materials Research
ResumoThe Raman spectra of p-benzoquinone, quinone-d4, quinone-18O2, quinone-d4-18O2, and quinone-2,5-d2, excited by the helium radiation 5875.6 Å, are reported, together with semiquantitative measurements of the intensities and qualitative observations on the state of polarization of the Raman shifts. The results are fully consistent with the D2h symmetry of the four molecular species mentioned first, the last one belonging to the point group C2h. A tentative assignment for all Raman-active fundamental vibrational modes of the investigated compounds is given.
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