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Noncovalent Functional‐Group–Arene Interactions

2007; Wiley; Volume: 46; Issue: 41 Linguagem: Inglês

10.1002/anie.200701463

1521-3773

William B. Motherwell, Joëlle Moïse, Abil E. Aliev, Miloslav Nič, Simon J. Coles, Peter N. Horton, Michael B. Hursthouse, Gianni Chessari, Christopher A. Hunter, Jeremy G. Vinter,

Molecular Spectroscopy and Structure

Angewandte Chemie International EditionVolume 46, Issue 41 p. 7823-7826 Communication Noncovalent Functional-Group–Arene Interactions† William B. Motherwell Prof., William B. Motherwell Prof. w.b.motherwell@ucl.ac.uk Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorJoëlle Moïse Dr., Joëlle Moïse Dr. Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorAbil E. Aliev Dr., Abil E. Aliev Dr. a.e.aliev@ucl.ac.uk Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorMiloslav Nič Dr., Miloslav Nič Dr. Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorSimon J. Coles Dr., Simon J. Coles Dr. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UKSearch for more papers by this authorPeter N. Horton Dr., Peter N. Horton Dr. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UKSearch for more papers by this authorMichael B. Hursthouse Prof., Michael B. Hursthouse Prof. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UKSearch for more papers by this authorGianni Chessari Dr., Gianni Chessari Dr. Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, UKSearch for more papers by this authorChristopher A. Hunter Prof., Christopher A. Hunter Prof. Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, UKSearch for more papers by this authorJeremy G. Vinter Dr., Jeremy G. Vinter Dr. Cresset Biomolecular Discovery, Spirella Building, Bridge Road, Letchworth SG6 4ET, UKSearch for more papers by this author William B. Motherwell Prof., William B. Motherwell Prof. w.b.motherwell@ucl.ac.uk Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorJoëlle Moïse Dr., Joëlle Moïse Dr. Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorAbil E. Aliev Dr., Abil E. Aliev Dr. a.e.aliev@ucl.ac.uk Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorMiloslav Nič Dr., Miloslav Nič Dr. Department of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London, WC1H 0AJ, UK, Fax: (+44) 20-7679-7463Search for more papers by this authorSimon J. Coles Dr., Simon J. Coles Dr. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UKSearch for more papers by this authorPeter N. Horton Dr., Peter N. Horton Dr. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UKSearch for more papers by this authorMichael B. Hursthouse Prof., Michael B. Hursthouse Prof. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UKSearch for more papers by this authorGianni Chessari Dr., Gianni Chessari Dr. Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, UKSearch for more papers by this authorChristopher A. Hunter Prof., Christopher A. Hunter Prof. Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, UKSearch for more papers by this authorJeremy G. Vinter Dr., Jeremy G. Vinter Dr. Cresset Biomolecular Discovery, Spirella Building, Bridge Road, Letchworth SG6 4ET, UKSearch for more papers by this author First published: 04 October 2007 https://doi.org/10.1002/anie.200701463Citations: 59 † We are grateful for the provision of studentships from Organon (J.M.) and Dr. Alfred Bader (M.N.) Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Hanging in the balance: A series of dibenzobicyclo[3,2,2]nonanes provides a delicate conformational balance for investigating weak interactions, such as OH⋅⋅⋅π(Ar) π-hydrogen bonding (see scheme, red O) and solvent–solute interactions. The models are designed to probe the effectiveness of replacing a hydroxy group by fluorine or to compare the arene affinities of sulfur and oxygen. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z701463_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume46, Issue41October 15, 2007Pages 7823-7826 RelatedInformation