Convenient syntheses of l-glycero-d-manno-heptose and d-glycero-d-manno-heptose
1986; Elsevier BV; Volume: 152; Linguagem: Inglês
10.1016/s0008-6215(00)90316-1
ISSN1873-426X
AutoresJ. S. Brimacombe, A. K. M. S. KABIR,
Tópico(s)Microbial Metabolites in Food Biotechnology
ResumoStereoselective synthesis of d-glycero- and l-glycero-β-d-mannoheptosides has been achieved by cesium carbonate-mediated β-selective anomeric O-alkylation of the corresponding d-mannoheptoses. In addition, this method has been utilized in the total synthesis of a tetrasaccharide repeat unit of Bacillus thermoaerophilus surface-layer glycoprotein.
Referência(s)