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Compounds with molecular asymmetry due solely to a tercovalent non-bridgehead nitrogen atom: optically active N-chloro-2,2-diphenylaziridine

1972; Royal Society of Chemistry; Issue: 20 Linguagem: Inglês

10.1039/c39720001133

2050-5639

Rita Annunziata, Roberto Fornasier, Fernando Montanari,

Free Radicals and Antioxidants

Optically active N-chloro-2,2-diphenylaziridine, whose asymmetry is due solely to the chiral nitrogen atom, has been obtained by asymmetric chlorination of 2,2-diphenylaziridine by (1R:2R)-(–)-isobornyl hypochlorite and (S)-(+)-(N-chloro)methylphenylsulphoximide.