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Structural study of sol–gel Au/TiO2 films from nanopowders

2010; Elsevier BV; Volume: 257; Issue: 9 Linguagem: Inglês

10.1016/j.apsusc.2010.12.024

1873-5584

D. Crışan, Nicolae Drăgan, Mălina Răileanu, Maria Crışan, Adelina Ianculescu, Dumitru Luca, Andrei Vasile Nastuta, Diana Mardare,

Catalytic Processes in Materials Science

TiO2 represents one of the most important sol–gel materials, due to its photocatalytic properties, in the case of both powders and coatings. Nanostructured titania has been reported to be used in many applications in different fields ranging from optics to gas sensor via solar energy. Recent researches point out the existence of new procedures used in order to enhance the efficiency of the photocatalytic process. The metal ion doping is such an example. Two types of 2 wt.% Au containing TiO2 powders have been embedded in sol–gel vitreous TiO2 matrices. Au-doped TiO2 films have been prepared from these sols, by dipping procedure using quartz microscopic slides, as substrates. The relationship between the synthesis conditions and the properties of titania nanosized materials, such as thermal stability, phase composition, crystallinity, and the influence of dopant was investigated. The hydrophilic properties of the films were correlated with their structure, composition and surface morphology.