A conformational model of per-O-acetyl-cyclomaltoheptaose (-β-cyclodextrin) in solution: detection of partial inversion of glucopyranose units by NMR spectroscopy
2003; Elsevier BV; Volume: 338; Issue: 10 Linguagem: Inglês
10.1016/s0008-6215(03)00074-0
ISSN1873-426X
AutoresGloria Uccello‐Barretta, Giuseppe Sicoli, Federica Balzano, Piero Salvadori,
Tópico(s)Enzyme Structure and Function
ResumoThe stereochemical features of per-O-acetyl-cyclomaltoheptaose (-beta-cyclodextrin) have been investigated in solution by NMR spectroscopy, and the deviation of functionalised glucopyranose rings from 4C(1) chairs to skew-type conformations has been detected.
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