Molecular Structure of an Unusual Organoactinide Hydride Complex Determined Solely by Neutron Diffraction
1979; American Association for the Advancement of Science; Volume: 203; Issue: 4376 Linguagem: Inglês
10.1126/science.203.4376.172
ISSN1095-9203
AutoresRobert W. Broach, Arthur J. Schultz, Jack M. Williams, G. M. Brown, Juan M. Manríquez, Paul J. Fagan, Tobin J. Marks,
Tópico(s)Crystal structures of chemical compounds
ResumoThe structure of an unusual organometallic complex, {Th[(CH(3))(5)C(5)](2) H(micro-H)}(2) . C(6)H(5)CH(3), has been determined from neutron diffraction data, using only the direct-methods program MULTAN. Besides providing accurate metrical information on the first organometallic actinide hydride complex, these results have general and far-reaching implications concerning the complexity and size of crystal structures that can be elucidated solely on the basis of neutron diffraction data.
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