Die Synthese und Stereochemie des Ergotamins. (58. Mitteilung über Mutterkornalkaloide
1963; Wiley; Volume: 46; Issue: 6 Linguagem: Inglês
10.1002/hlca.19630460650
ISSN1522-2675
AutoresA. Hofmann, H. Ott, R. Griot, P. A. Stadler, A. Frey,
Tópico(s)Advanced Synthetic Organic Chemistry
ResumoAbstract A stereospecific synthesis of ergotamine is described which confirms the postulated formula containing a cyclol structure. During this work it was also possible to determine the previously unknown configurations at the asymmetric centers C‐2′ and C‐12′.
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