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A total asymmetric synthesis of the isolactarane sesquiterpene (−)-merulidial

1992; Elsevier BV; Volume: 33; Issue: 32 Linguagem: Inglês

10.1016/s0040-4039(00)61307-2

1873-3581

Barry M. Trost, Philip A. Hipskind,

Synthetic Organic Chemistry Methods

A general strategy for the synthesis of lactaranes, marasmanes, sterpuranes as well as isolactaranes which share a common structural motif begins to emerge based upon a tandem Pd catalyzed cycloisomerization - thermal cycloaddition sequence.