Voltar
Artigo Produção Nacional
BIBTEX RIS

(p-Anisaldehyde thiosemicarbazonato)dimethylthallium( III ): an unusual structure for a co-ordinated thiosemicarbazone

1993; Royal Society of Chemistry; Issue: 2 Linguagem: Inglês

10.1039/dt9930000353

ISSN

2050-5671

Autores

José S. Casas, E.E. Castellano, A. Macías, M.C. Rodríguez-Argüelles, A. Sánchez, J. Sordo,

Tópico(s)

Magnetism in coordination complexes

Resumo

Reaction of an ethanolic solution of p-anisaldehyde thiosemicarbazone (HL) with an aqueous [TlMe2(OH)] solution afforded the compound [TIMe2L] in which the deprotonated thiosemicarbazone retains the typical structure of free thiosemicarbazones, an unusual arrangement of this type of ligand in a metallic complex.

Referência(s)