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Pushing the limits of steric demand around a biaryl axis: synthesis of tetra-ortho-substituted biaryl naphthalenes

2010; Royal Society of Chemistry; Volume: 47; Issue: 1 Linguagem: Inglês

10.1039/c0cc02170a

1364-548X

Adam Glass, Sam Klonoski, Lev N. Zakharov, Shih‐Yuan Liu,

Catalytic Cross-Coupling Reactions

The synthesis of tetra-ortho-substituted biaryl naphthalenes, including examples bearing multiple ortho-isopropyl groups, has been developed via a catalytic rearrangement process.