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BIBTEX RIS

X-Ray Diffraction Studies on the Structures of Diammine- and Aquasilver(I) Complexes in Aqueous Solution

1979; Oxford University Press; Volume: 52; Issue: 9 Linguagem: Inglês

10.1246/bcsj.52.2545

ISSN

1348-0634

Autores

Masunobu Maeda, Yoshiteru Maegawa, Toshio Yamaguchi, Hitoshi Ohtaki,

Tópico(s)

Catalysis and Oxidation Reactions

Resumo

Abstract X-Ray diffraction studies were carried out for aqueous diamminesilver(I) nitrate, silver(I) perchlorate and nitrate solutions. The radial distribution curve of the diamminesilver(I) nitrate solution showed that the length of the Ag–NH3 bond is (2.22±0.02) Å. In the aqueous silver(I) perchlorate solution, a silver(I) ion is combined with two water molecules at a distance of (2.41±0.02) Å, the result being in good agreement with that obtained for the nitrate solution.

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