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Structure of Dimethylthallium Compounds Soluble in Non-polar Solvents

1967; Oxford University Press; Volume: 40; Issue: 4 Linguagem: Inglês

10.1246/bcsj.40.861

1348-0634

Hideo Kurosawa, Kiyoshi Yasuda, Rokuro Okawara,

Solid-state spectroscopy and crystallography

Abstract Several dimethylthallium derivatives were studied by means of a study of their IR and NMR spectra and by measurements of their physical properties. These new compounds, (CH3)2· TlSC6H5, (CH3)2TlOC6H4Cl-o, and (CH3)2Tl[B(C6H5)], are described. By correlation with earlier reports, it is possible to classify dimethylthallium derivatives into two groups according to the nature of the hybridization of the Tl-bonding orbitals. The experimental results can be interpreted in a straightforward and consistent manner.