Bis and tetrakis(6-methyl-1,4-dithiafulven-6-yl) substituted tetrathiafulvalenes (TTF) and their vinylogs as novel π-donors
1997; Elsevier BV; Volume: 38; Issue: 8 Linguagem: Inglês
10.1016/s0040-4039(97)00035-x
ISSN1873-3581
AutoresPhilippe Leriche, Ahmed Belyasmine, Marc Sallé, Alain Gorgues, Michel Jubault, Javier Garı́n, J. Orduna,
Tópico(s)Vanadium and Halogenation Chemistry
ResumoThe synthesis of highly extended and sulfur rich tetrathiafulvalene derivatives, designed to avoid any internal cyclisation during their subsequent electrooxidation, is described. Their π-donating ability is confirmed by cyclic voltammetry, as well as the good stability of each of their oxidized species (up to an hexacationic state in one case).
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