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Chlorocarbon Activation: Catalytic Carbonylation of Dichloromethane and Chlorobenzene

1989; Wiley; Volume: 28; Issue: 10 Linguagem: Inglês

10.1002/anie.198913861

1521-3773

Marc Huser, Marie Therese Youinou, John A. Osborn,

Carbon dioxide utilization in catalysis

Angewandte Chemie International Edition in EnglishVolume 28, Issue 10 p. 1386-1388 Communication Chlorocarbon Activation: Catalytic Carbonylation of Dichloromethane and Chlorobenzene† Dr. Marc Huser, Dr. Marc Huser Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Search for more papers by this authorDr. Marie- Thérèse Youinou, Dr. Marie- Thérèse Youinou Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Search for more papers by this authorProf. Dr. John A. Osborn, Corresponding Author Prof. Dr. John A. Osborn Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut Le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Search for more papers by this author Dr. Marc Huser, Dr. Marc Huser Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Search for more papers by this authorDr. Marie- Thérèse Youinou, Dr. Marie- Thérèse Youinou Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Search for more papers by this authorProf. Dr. John A. Osborn, Corresponding Author Prof. Dr. John A. Osborn Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Laboratoire de Chimie des Métaux de Transition et de Catalyse, UA au, CNRS n° 424, Université Louis Pasteur, Institut Le Bel 4, rue Blaise Pascal, F-67000 Strasbourg (France)Search for more papers by this author First published: October 1989 https://doi.org/10.1002/anie.198913861Citations: 107 † Rhǒne-Poulenc is thanked for a Gaduate Fellowship (M.H.) and for financial support. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Catalytic reactions of the type dichloromethane → ketene and chlorobenzene → benzoic acid esters (or benzaldehyde) are possible with Pd complexes, although the turnover numbers are still small. The CCl bond in CH2C12 is even activated by [Pd(PCy3)2(dba)]/PCy3 and the CCl bond in PhCI by Pd(CH3COO)2/PCy3 (Cy = cyclohexyl). The nature of the phosphane is decisive in these reactions : their basicity and cone angle must lie within a certain range. Initial products in the carbonylation are complexes 1 and 2. Citing Literature Volume28, Issue10October 1989Pages 1386-1388 RelatedInformation