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A host–guest complex between a metal–organic cyclotriveratrylene analog and a polyoxometalate: [Cu 6 (4,7-phenanthroline) 8 (MeCN) 4 ]2PM 12 O 40 (M = Mo or W)

2004; Royal Society of Chemistry; Issue: 5 Linguagem: Inglês

10.1039/b309255k

1364-548X

J.M. Knaust, C. Inman, Steven W. Keller,

Chemical Synthesis and Reactions

The synthesis and crystal structure of Cu(6)(4,7-phenanthroline)(8)(MeCN)(4)(6+) a novel Cu(i)-molecular hexamer is described in which the metal cations and phenanthroline molecules self-assemble into a dimer of shallow triangular-shaped bowls, within which are located large spherical polyoxometalate anions PM(12)O(40)(3-)(M = Mo or W).