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N-nitrosamines the phase-transfer mediated nitrosation of secondary amines with sodium nitrite and n-haloamides

1984; Elsevier BV; Volume: 25; Issue: 25 Linguagem: Inglês

10.1016/s0040-4039(01)81245-4

1873-3581

Masayuki Nakajima, John C. Warner, J.‐P. Anselme,

Chemical Synthesis and Reactions

Secondary amines are cleanly and readily converted to the corresponding N-nitrosamines in high yield under phase-transfer conditions by means of soduim nitrite and N-halo-amides; the active nitrosating agent is presumed to be dinitrogen tetroxide.