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Synthesis and Characterization of a Tetrazolate-Bridged Coordination Framework Encapsulating D 2 h -Symmetric Cyclic (H 2 O) 4 Cluster Arrays

2004; American Chemical Society; Volume: 43; Issue: 20 Linguagem: Inglês

10.1021/ic0492946

1520-510X

Jun Tao, Zhijie Ma, Rong‐Bin Huang, Lan‐Sun Zheng,

Synthesis and Characterization of Heterocyclic Compounds

Reaction of 5,5'-(1,4-phenylene)bis(1H-tetrazole), which was prepared in two steps, with cadmium nitrate in DMF produced a three-dimensional framework with one-dimensional channels (35% void volume), in which unprecedented hydrogen-bond-supported D2h tetrameric cyclic water clusters ranked.