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A Self‐Supported Polymeric MacMillan Catalyst for Homogeneous Organocatalysis and Heterogeneous Recycling

2013; Wiley; Volume: 8; Issue: 6 Linguagem: Inglês

10.1002/asia.201300152

1861-4728

Chang An Wang, Yuan Zhang, Jiao Yi Shi, Wei Wang,

Axial and Atropisomeric Chirality Synthesis

Lean on me: A soluble, "self-supported" chiral organosilica polymer (ChiOSP) with embedded imidazolidinone catalytic moieties was synthesized by a bottom-up strategy and applied as a highly efficient and recyclable organocatalyst for the asymmetric Diels-Alder reaction.