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Catalytic supercritical fluid extraction: selective hydroformylation of olefin mixtures using scCO2 solubility for differentiation

2010; Royal Society of Chemistry; Volume: 12; Issue: 10 Linguagem: Inglês

10.1039/c0gc00299b

1463-9270

Timo Koch, Simon Desset, Walter Leitner,

Analytical Chemistry and Chromatography

A new reaction concept that allows one to control the substrate selectivity of a catalytic reaction by supercritical fluid extraction is demonstrated for the hydroformylation of long-chain olefins as a prototypical example.