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Mutual Capture of Dipolar Molecules at Low and Very Low Energies. I. Approximate Analytical Treatment

2010; American Chemical Society; Volume: 114; Issue: 36 Linguagem: Inglês

10.1021/jp102098j

1520-5215

E. E. Nikitin, J. Troe,

Atomic and Molecular Physics

Approximate analytical expressions are derived for the low-energy rate coefficients of capture of two identical dipolar polarizable rigid rotors in their lowest nonresonant (j(1) = 0 and j(2) = 0) and resonant (j(1) = 0,1 and j(2) = 1,0) states. The considered range extends from the quantum, ultralow energy regime, characterized by s-wave capture, to the classical regime described within fly wheel and adiabatic channel approaches, respectively. This is illustrated by the table of contents graphic (available on the Web) that shows the scaled rate coefficients for the mutual capture of rotors in the resonant state versus the reduced wave vector between the Bethe zero-energy (left arrows) and classical high-energy (right arrow) limits for different ratios δ of the dipole-dipole to dispersion interaction.