Kernresonanzspektroskopie mit Natrium-23
1978; Wiley; Volume: 90; Issue: 4 Linguagem: Eslovaco
10.1002/ange.19780900407
ISSN1521-3757
Autores Tópico(s)Mass Spectrometry Techniques and Applications
ResumoAngewandte ChemieVolume 90, Issue 4 p. 271-283 Aufsatz Kernresonanzspektroskopie mit Natrium-23 Prof. Dr. Pierre Laszlo, Prof. Dr. Pierre Laszlo Institut de Chimie, Université de Liège Sart-Tilman par 4000 Liège I (Belgien)Search for more papers by this author Prof. Dr. Pierre Laszlo, Prof. Dr. Pierre Laszlo Institut de Chimie, Université de Liège Sart-Tilman par 4000 Liège I (Belgien)Search for more papers by this author First published: April 1978 https://doi.org/10.1002/ange.19780900407Citations: 44AboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Die Entwicklung der Fourier-Transform-Technik hat die 23Na-NMR-Spektroskopie zu einem wichtigen Hilfsmittel werden lassen, mit dem der Organiker wie der Bio-Anorganiker Phänomene der Solvatation und der Ionenpaar-Bildung direkt beobachten kann. Die chemische Verschiebung und die Linienbreite von 23Na-Signalen erschließen Komplexstabilitätskonstanten, Korrelationszeiten von Reorientierungsvorgängen und die Mikrodynamik in der Koordinationssphäre des Natrium-Ions. In Konkurrenzexperimenten können mit der 23Na-NMR-Spektroskopie auch die Bindungsverhältnisse weiterer Kationen studiert werden. References 1 R. J. P. Williams, Q. Rev. Chem. Soc. 1970, 331. Google Scholar 2 R. J. P. Williams, Adv. Chem. Ser. 100, 155 (1971). 10.1021/ba-1971-0100.ch008 Google Scholar 3 H. Sigel: Metal Ions in Biological Systems. Vol. 1. Marcel Dekker, New York 1973. Google Scholar 4 I. M. Glynn, J. Physiol. 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