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Cu II Coordination Complex Involving TTF-py as Ligand

2001; American Chemical Society; Volume: 40; Issue: 26 Linguagem: Inglês

10.1021/ic015550s

1520-510X

Fumiyasu Iwahori, Stéphane Golhen, Lahcène Ouahab, R. Carlier, Jean‐Pascal Sutter,

Porphyrin and Phthalocyanine Chemistry

The novel complex trans-Cu(hfac)2(TTF-py)2 (hfac = hexafluoroacetylacetonate; TTF-py = 4-(2-tetrathiafulvalenyl-ethenyl)pyridine) in which the paramagnetic transition metal and the organic donor are covalently linked through a conjugated bridge is synthesized and characterized aiming at a new approach for the occurrence of π−d interactions in conducting and magnetic molecule-based materials.