Acid-catalyzed rearrangement of pyran derivatives. An approach to the stereoselective synthesis of 1,3-diol derivatives
1989; Elsevier BV; Volume: 30; Issue: 22 Linguagem: Inglês
10.1016/s0040-4039(00)99149-4
ISSN1873-3581
AutoresPhilip DeShong, David Simpson, Ming-Teh Lin,
Tópico(s)Asymmetric Synthesis and Catalysis
ResumoPeracid oxidation and HF-catalyzed treatment of furfuryl alcohol derivatives affords lactone products arising from a highly stereoselective rearrangement process. The lactones serve as precursors of highly functionalized anti-1,3-diol derivatives.
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