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Dielectric studies of non-electrolyte solutions. Part 1.—Electric permittivity and non-linear behaviour of mixtures of polar anisotropic molecules.

1972; Royal Society of Chemistry; Volume: 68; Linguagem: Inglês

10.1039/f29726801253

2050-5663

Jean-Marie Thiébaut, Jean‐Louis Rivail, Jean Barriol,

Spectroscopy and Quantum Chemical Studies

A modification of Onsager's model taking into account molecular anisotropy is proposed for mixtures of polar liquids. Two formulae giving the concentration dependence of the electric permittivity and its variations under the influence of strong electric fields (dielectric saturation) are derived.