Tetra‐ tert ‐butyltetraphosphacubane: The First Thermal Cyclooligomerization of a Phosphaalkyne
1989; Wiley; Volume: 28; Issue: 8 Linguagem: Inglês
10.1002/anie.198910131
ISSN1521-3773
AutoresThomas Wettling, Jürgen E. Schneider, Oliver Wagner, Cornelius G. Kreiter, Manfred Regitz,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoAngewandte Chemie International Edition in EnglishVolume 28, Issue 8 p. 1013-1014 Communication Tetra-tert-butyltetraphosphacubane: The First Thermal Cyclooligomerization of a Phosphaalkyne†‡ Dipl.-Chem. Thomas Wettling, Dipl.-Chem. Thomas Wettling Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Jürgen Schneider, Dipl.-Chem. Jürgen Schneider Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Oliver Wagner, Dipl.-Chem. Oliver Wagner Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Cornelius G. Kreiter, Prof. Dr. Cornelius G. Kreiter Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Manfred Regitz, Corresponding Author Prof. Dr. Manfred Regitz Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this author Dipl.-Chem. Thomas Wettling, Dipl.-Chem. Thomas Wettling Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Jürgen Schneider, Dipl.-Chem. Jürgen Schneider Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorDipl.-Chem. Oliver Wagner, Dipl.-Chem. Oliver Wagner Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Cornelius G. Kreiter, Prof. Dr. Cornelius G. Kreiter Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Manfred Regitz, Corresponding Author Prof. Dr. Manfred Regitz Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Fachbereich Chemie der Universität, Erwin-Schrödinger-Strase, D-6750 Kaiserslautern (FRG)Search for more papers by this author First published: August 1989 https://doi.org/10.1002/anie.198910131Citations: 123 † Unusual Coordinated Phosphorus Compounds, Part 37. This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. Part 36: W. Schnurr, M. Regitz, Synthesis 1989, im Druck. ‡ Dedicated to Professor Gottfried Märkl on the occasion of his 60th birthday AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A previously unknown reaction of phosphaalkynes, the thermal cyclotetramerization of 1, leads in one step to the title compound 2 (65 h at 130°C in a glass pressure tube, neat). Compound 2 is pale yellow and air stable. The NMR signals of the cage atoms are unusual: δ(13C)= −29.07, δ(31P)= + 257.4. Citing Literature Volume28, Issue8August 1989Pages 1013-1014 RelatedInformation
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