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Novel Ag/Li4Ti5O12 binary composite anode electrodes for high capacity Li-ion batteries

2015; Elsevier BV; Volume: 271; Linguagem: Inglês

10.1016/j.surfcoat.2014.12.067

1879-3347

Aslıhan Erdaş, Şeyma Özcan, Deniz Nalci, Aslıhan Güler, Hatem Akbulut,

Supercapacitor Materials and Fabrication

In this study, spinel lithium titanates, Li4Ti5O12, have been synthesized by a simple sol–gel method. Surfaces of as-synthesized Li4Ti5O12 powders were then coated with silver. Electrochemical results exhibit that Ag/Li4Ti5O12 has a highest lithium storage capacity of 175 mAh g− 1 and Li4Ti5O12 displays the lowest initial charge capacity of 170 mAh g−1 . The synthesized Ag/Li4Ti5O12 composite electrode also showed the significantly improved high-rate capability and stability, which delivered initial discharge capacity of 170, 147, 118, 99, 88, 77, 66, 56, 46 and 34 mAh g−1 at the charge/discharge current density of 1, 2, 4, 8, 10, 20, 30, 40, 60 and 80 C, respectively. The sol–gel and electroless deposition processes may present a facile pathway for large-scale preparation of Ag/Li4Ti5O12 as high-performance anode materials for lithium-ion batteries.