Flash Photolysis of Matrix-Isolated Cyanogen Azide in Solid Nitrogen
1966; American Institute of Physics; Volume: 45; Issue: 8 Linguagem: Inglês
10.1063/1.1728024
ISSN1520-9032
Autores Tópico(s)Molecular Junctions and Nanostructures
ResumoFlash photolysis combined with matrix-isolation spectroscopy has been employed to investigate the decomposition of a cyanogen azide—nitrogen solid at 20.4°K. Two primary processes have been observed leading to the formation of NCN radicals either in an electronically excited 1Δg level or in the 3Σg− ground state. The first-order decay of NCN (1Δg) has been studied and the mean lifetime in the solid found to be approximately 500 μsec.
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