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Artigo Revisado por pares
BIBTEX RIS

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF 3 Complexes

2008; American Chemical Society; Volume: 130; Issue: 27 Linguagem: Inglês

10.1021/ja802946s

ISSN

1943-2984

Autores

Galyna G. Dubinina, Hideki Furutachi, David A. Vicic,

Tópico(s)

Inorganic Fluorides and Related Compounds

Resumo

The first examples of isolable and structurally characterized Cu(I)−CF3 complexes are reported. N-Heterocyclic carbene (NHC)-supported copper tert-butoxide complexes reacted with Me3Si−CF3 to afford new (NHC)Cu−CF3 complexes whose structures were dependent on whether or not the C4−C5 positions of the five-membered NHC rings were saturated. In situ generated (SIiPr)Cu−CF3 cleanly transferred its trifluoromethyl group to a number of organic halides under mild conditions.

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