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Vinyl carboxylate an acylating reagent for selective acylation of amines and diols

1994; Elsevier BV; Volume: 35; Issue: 21 Linguagem: Inglês

10.1016/s0040-4039(00)73245-x

1873-3581

S.-T. Chen, S.-Y. Chen, S.-J. Chen, K.-T. Wang,

Asymmetric Synthesis and Catalysis

Abstract Vinyl group of vinyl alkylate (C=2 or 16) and vinyl benzoate have been found to be a good leaving group in acylation of alcohols (40–50% yield) and amines (in 60–90% yield).