A simple new general synthesis of macrocyclic ketones: A new entry to the synthesis of exaltone and (±)-muscone
1987; Elsevier BV; Volume: 28; Issue: 34 Linguagem: Inglês
10.1016/s0040-4039(00)96432-3
ISSN1873-3581
AutoresHiroshi Suginome, Shinji Yamada,
Tópico(s)Marine Sponges and Natural Products
ResumoWe describe an efficient new synthesis of 15-membered cyclic ketones, exaltone and (±)-muscone, based on a three-carbon annelation of cyclic ketones followed by the regioselective radical cleavage of the fused bond of the resulting bicyclic systems.
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