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A Novel Antiferromagnetic Organic Superconductor κ-(BETS) 2 FeBr 4 [Where BETS = Bis(ethylenedithio)tetraselenafulvalene]

2000; American Chemical Society; Volume: 123; Issue: 2 Linguagem: Inglês

10.1021/ja002439x

1943-2984

Hideki Fujiwara, Emiko Fujiwara, Yasuhiro Nakazawa, B.Zh. Narymbetov, Kiyonori Kato, Hayao Kobayashi, Akiko Kobayashi, M. Tokumoto, P. Cassoux,

N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

The electrical and magnetic properties of kappa-(BETS)(2)FeBr(4) salt [where BETS = bis(ethylenedithio)tetraselenafulvalene] showed that this system is the first antiferromagnetic organic metal at ambient pressure (T(N) = 2.5 K). The characteristic field dependence of the magnetization at 2.0 K indicates a clear metamagnetic behavior. The small resistivity drop observed at T(N) clearly shows the existence of the interaction between pi metal electrons and localized magnetic moments of Fe(3+) ions. In addition, this system underwent a superconducting transition at 1.1 K. That is, kappa-(BETS)(2)FeBr(4) is the first antiferromagnetic organic metal exhibiting a superconducting transition below Néel temperature. The magnetic field dependence of the superconducting critical temperature indicated that the superconductivity in this system is strongly anisotropic also in the conduction plane because of the existence of the metamagnetically induced internal field based on the antiferromagnetic ordering of the Fe(3+) 3d spins in contrast to the cases of the other conventional organic superconductors. Furthermore, the specific heat measurement exhibited a lambda-type large peak of zero-field specific heat corresponding to the three-dimensional antiferromagnetic ordering of high-spin Fe(3+) ions. The lack of distinct anomaly in the C(p) vs T curve at T(c) suggests the coexistence of the superconductivity and the antiferromagnetic order below T(c).