Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions
1991; Elsevier BV; Volume: 32; Issue: 6 Linguagem: Inglês
10.1016/s0040-4039(00)74863-5
ISSN1873-3581
AutoresNed A. Porter, Wenxue Wu, Andrew T. McPhail,
Tópico(s)Chemical Synthesis and Analysis
ResumoCompetition rate constants were determined for the addition of cyclohexyl radical to α,β unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state
Referência(s)