Neue metallorganisch substituierte Indium-Chalkogen-Verbindungen mit In 4 E 4 -Heterokubangerüst (E = S, Se,Te)/New Organoindium Chalcogen Compounds with In 4 E 4 Heterocubane Structure (E = S, Se,Te)
1992; De Gruyter; Volume: 47; Issue: 4 Linguagem: Inglês
10.1515/znb-1992-0404
ISSN1865-7117
AutoresKurt Merzweiler, Frank Rudolph, Ludwig Brands,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoThe reaction of organometallic indium halides R 2 InBr and RInCl 2 (R = {Cp(CO) 2 Fe}, {Cp(CO) 3 Mo}) with silylated chalcogens E(SiMe 3 ) 2 (E = S, Se, Te) leads to the formation of cage compounds which contain a central In 4 E 4 cube. The structures of [{Cp(CO) 2 Fe} 4 In 4 Se 4 ] (1), [{Cp(CO) 3 Mo} 4 In 4 S 4 ] (2), [{Cp(CO) 2 Fe} 4 In 4 S 4 ] (3) and [{Cp(CO) 3 Mo} 4 In 4 Te 4 ] (4) were determined by X-ray crystallography.
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