Voltar
Artigo Revisado por pares
BIBTEX RIS

Fluxional five-coordinate platinum(II) complexes containing chelating triphosphine ligands

1977; Elsevier BV; Volume: 139; Issue: 2 Linguagem: Inglês

10.1016/s0022-328x(00)85485-6

ISSN

1872-8561

Autores

Kwoliang D. Tau, Devon W. Meek,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

Platinum(II) dimethyl complexes of the three triphosphines PhP(CH2CH2CH2PPh2)2, PhP(CH2CH2PPh2)2, and PhP(CH2CH2PMe2)2 have been shown by 31P NMR to undergo exchange of the terminal phosphino groups. An exchange route involving a five-coordinate platinum(II) complex is proposed.

Referência(s)