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Efficient fabrication of ZrO2-doped TiO2 hollow nanospheres with enhanced photocatalytic activity of rhodamine B degradation

2011; Elsevier BV; Volume: 364; Issue: 2 Linguagem: Inglês

10.1016/j.jcis.2011.07.055

1095-7103

Chuanzhi Sun, Lichen Liu, Lei Qi, Hao Li, Hongliang Zhang, Changshun Li, Fei Gao, Lin Dong,

Catalytic Processes in Materials Science

ZrO2-doped TiO2 hollow nanospheres with anatase phase are efficiently fabricated via functionalized negatively charged polystyrene (PS) spheres without any surfactant or polyelectrolyte. The resulting Ti1−xZrxO2 (hereafter denoted as TZ) hollow nanospheres are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), Laser Raman spectroscopy (LRS), X-ray photoelectron spectroscopy (XPS), X-ray fluorescence spectroscopy (XRF), nitrogen sorption, and UV–vis diffuse reflectance spectroscopy (UV–vis). The Zr4+ incorporation decreases the anatase crystallite size, increases the specific surface area, and changes the pore size distribution. Furthermore, it induces enrichment of electron charge density around Ti4+ ions and blueshift of absorption edges. The TZ hollow nanospheres doped with moderate ZrO2 (molar ratio, Ti:Zr = 10:1) exhibit better photocatalytic activity than the other samples for the degradation of rhodamine B in aqueous solution, which is correlated with the effect of Zr4+ doping on the physicochemical properties in terms of surface structures, phase structures, and the electronic structures.