The far-infrared spectra of solid H2S and D2S at 5°K and 77°K
1965; Elsevier BV; Volume: 21; Issue: 11 Linguagem: Inglês
10.1016/0371-1951(65)80240-5
ISSN1873-3816
AutoresP. Taimsalu, Dean W. Robinson,
Tópico(s)Molecular Spectroscopy and Structure
ResumoThe infrared spectra of solid H2S and D2S have been recorded between 350 and 60 cm−1 at 5°K and 77°K. Both substances gave five bands of librational and four of translational origin. On cooling to 5°K the bands show considerable sharpening and a small shift to higher frequencies. The observed spectra fit reasonably well with the group-theoretical prediction based on a structure P42(C3)4 for H2S.
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