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Palladium-Catalyzed Oxime Assisted Intramolecular Dioxygenation of Alkenes with 1 atm of Air as the Sole Oxidant

2010; American Chemical Society; Volume: 132; Issue: 18 Linguagem: Inglês

10.1021/ja100716x

1943-2984

Ming‐Kui Zhu, Junfeng Zhao, Teck‐Peng Loh,

Synthesis and Catalytic Reactions

This paper describes a palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes by using 1 atm of air as the sole oxidant under extremely mild conditions, which demonstrated the feasibility of incorporating atmospheric oxygen into synthetically useful products under 1 atm of air at room temperature.