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Hydration constants of perchlorate anion in nitrobenzene solution of tris(1,10-phenanthroline)iron(II) or tris(2,2′-bipyridine)iron(II) perchlorate

1975; Pergamon Press; Volume: 37; Issue: 5 Linguagem: Inglês

10.1016/0022-1902(75)80471-4

1878-1225

Takao Tarui,

Electrochemical Analysis and Applications

Abstract From isopiestic measurements, hydration constants of the perchlorate ion in nitrobenzene solution of Fe(phen)3(ClO4)2 or Fe(bipy)3(ClO4)2 were estimated using five models, and compared with each other to obtain the best-fit model. We conclude that the mono- and di-hydrate model is the most reasonable.