The Molecular Structure of Dimethyltrisulfide, (CH3)2S3
1948; American Institute of Physics; Volume: 16; Issue: 2 Linguagem: Inglês
10.1063/1.1746822
ISSN1520-9032
AutoresJerry Donohue, Verner Schomaker,
Tópico(s)Chemical Thermodynamics and Molecular Structure
ResumoDimethyltrisulfide (CH3)2S3 has been investigated by the electron diffraction method. The molecule was found to have the chain configuration, with the following interatomic distances and angles: C–H=1.09A (assumed), C–S=1.78±0.04A, S–S=2.04A, ±0.02A, ∠H–C–S=112° (assumed), ∠S–S–S=104°±5°, and ∠C–S–S=104°±5°. The results also suggest that the C–S bonds oscillate with rather large amplitude about a mean position approximately 106° out of the plane of the three sulfur atoms.
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