(Perylene) 3 [Bi 4 Br 12 ]: A New Arene π-Complex Containing the [Bi 4 Br 12 ] Unit
1996; American Chemical Society; Volume: 35; Issue: 8 Linguagem: Inglês
10.1021/ic950986r
ISSN1520-510X
AutoresL. P. BATTAGLIA, Carlo Bellitto, Maria Rita Cramarossa, Ida Maria Vezzosi,
Tópico(s)Ionic liquids properties and applications
ResumoThe reaction of perylene with anhydrous bismuth bromide leads to a new structurally characterized π-arene complex. Arene−bismuth interactions and weak π···π perylene−perylene contacts stabilize the molecular framework of tetrameric Bi4Br12 in the solid state. A one-dimensional arene−tetrameric unit−arene packing motif is observed.
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