Portal de Periódicos da CAPES

An Evolutionary Approach to the Estimation of Reactivity Ratios

2002; Wiley; Volume: 11; Issue: 5 Linguagem: Inglês

10.1002/1521-3919(20020601)11

1521-3919

Dagmar Monett, José Alberto Méndez, Gustavo A. Abraham, Alberto Gallardo, Julio San Román,

Advanced Polymer Synthesis and Characterization

Here we apply evolutionary techniques to the calculation of copolymerization reactivity ratios from an inverse problem perspective. To estimate monomer reactivity ratios, we take into account the main aspects of both inverse problems and evolutionary computation techniques. Copolymers of methyl methacrylate (MMA) and α-tocopheryl methacrylate (MVE) were prepared by free radical copolymerization in dioxane solution using 2,2′-azoisobutyronitrile as the initiator. The reactivity ratios were calculated according to the general copolymerization equation using the Fineman–Röss and Kelen–Tüdos linearization methods, as well as the Tidwell–Mortimer nonlinear least-squares treatment. Reactivity ratios were compared with four different simulations of an evolutionary approach that implements a genetic algorithm. The reactivity ratios obtained with these four simulations were similar, the values being rMMA = 0.92 and rMVE = 1.00. Results obtained with the application of evolutionary techniques demonstrate high-quality solutions and show the convenient use by estimating monomer reactivity ratios in MMA-co-MVE (copolymer of MMA and MVE), a chain addition copolymerization system with potential biomedical applications. The numerous advantages of genetic parameters, performance, and major features of genetic algorithms, are also discussed.