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Synthesis and Characterization of the First Compounds Containing a Stable Phosphirenyl Cation: Crystal and Molecular Structure of [Ni(η 3 ‐PC 2 t Bu 2 )(η 5 ‐P 3 C 2 t Bu 2 )W(CO) 5 ]

1994; Wiley; Volume: 33; Issue: 22 Linguagem: Inglês

10.1002/anie.199423301

1521-3773

Anthony G. Avent, F. Geoffrey N. Cloke, Kevin R. Flower, Peter B. Hitchcock, John F. Nixon, David Vickers,

Organometallic Complex Synthesis and Catalysis

Angewandte Chemie International Edition in EnglishVolume 33, Issue 22 p. 2330-2332 Communication Synthesis and Characterization of the First Compounds Containing a Stable Phosphirenyl Cation: Crystal and Molecular Structure of [Ni(η3-PC2tBu2)(η5-P3C2tBu2)W(CO)5]† Dr. Anthony G. Avent, Dr. Anthony G. Avent School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorProf. Dr. F. Geoffrey N. Cloke, Prof. Dr. F. Geoffrey N. Cloke School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorDr. Kevin R. Flower, Dr. Kevin R. Flower School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorDr. Peter B. Hitchcock, Dr. Peter B. Hitchcock School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorProf. Dr. John F. Nixon, Corresponding Author Prof. Dr. John F. Nixon School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorDavid M. Vickers, David M. Vickers School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this author Dr. Anthony G. Avent, Dr. Anthony G. Avent School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorProf. Dr. F. Geoffrey N. Cloke, Prof. Dr. F. Geoffrey N. Cloke School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorDr. Kevin R. Flower, Dr. Kevin R. Flower School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorDr. Peter B. Hitchcock, Dr. Peter B. Hitchcock School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorProf. Dr. John F. Nixon, Corresponding Author Prof. Dr. John F. Nixon School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this authorDavid M. Vickers, David M. Vickers School of Chemistry and Molecular Sciences, University of Sussex, GB-Brighton, BN1 9QJ, Sussex (UK), Telefax: Int. code +(273)677196Search for more papers by this author First published: December 5, 1994 https://doi.org/10.1002/anie.199423301Citations: 40 † We thank the Engineering and Physical Sciences Research Council for their continuing support of our work. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Cocondensation of Ni vapor with the phosphaalkyne tBuP affords complex 1, which can be substituted at the P3C2 ring with W(CO)5 to give 2. The presence of the first stable phosphirenyl cation was confirmed by spectroscopy and X-ray crystallography. Citing Literature Volume33, Issue22December 5, 1994Pages 2330-2332 RelatedInformation