Portal de Periódicos da CAPES

Free radical reactions in solution VIII. Radical-initiated addition of trialkylsilanes across alkene C=C bonds

1982; Elsevier BV; Volume: 232; Issue: 1 Linguagem: Inglês

10.1016/s0022-328x(82)80005-3

1872-8561

Nabil M.K. El-Durini, Richard A. Jackson,

Catalytic C–H Functionalization Methods

Difficulties in carrying out the free-radical addition of trialkylsilanes (as opposed to trichlorosilane) to alkene C=C bonds are partly due to telomerization competing with the radical transfer step. This can be overcome by the use of a large excess of trialkylsilane, when good yields of adduct are obtained from mono-substituted and 1,2-disubstituted alkenes.